Product ID:FLUOROCARBON 113
MSDS Date:01/01/1985
FSC:6850
NIIN:00-319-0834
MSDS Number: BDWSH

Emergency Phone: OUT OF BUSINESS

Cage: 86511

Telephone: OUT OF BUSINESS

Cage: 86511

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 99.9%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 43G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:(HMIS INFORMATION-EYES: MAY CAUSE
CONJUNCTIVITIS. SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE
IRRITATION, DEFATTING OF SKIN AND DERMATITIS. INHALATION: HIGH
LEVELS CAN CAUSE NERVOUS SYSTEM DEPRESSIO N, CARDIAC ARRYTHMIA. AT
LOW CONCENTRATIONS MAY CAUSE HEADACHE. INGESTION: LOW TO MODERATE
TOXICITY. HMIS).
Effects of Overexposure:EYE:IRRIT.SKIN:DEFATS.LOW ORAL TOXIC.INHAL:
DROWSINESS,HEADACHE,GIDDINESS.UNCON/DEATH IF EXPOS SEVERE
Medical Cond Aggravated by Exposure:(HMIS-DISEASES OF THE LIVER,
RETINA, CENTRAL NERVOUS SYSTEM.-HMIS)

First Aid:INHAL:MOVE TO FRESH AIR.KEEP WARM.GET MEDICAL ATTN.IS
ANESTHETIC-DO NOT GIVE SYMPATHOMINETIC DRUGS LIKE ADRENALINE.GIVE
ART RESPIR IF BREATH STOP.EYE:FLUSH W/WATER FOR 15 MIN. INGEST:GIVE
2 GLASSES WA TER & INDUCE VOMITING BY FINGER DOWN THROAT.

Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. KEEP
CONTAINERS COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTACT W/NAKED FLAME OR RED HOT SURFACES
CAUSE ACIDIC DECOMPOSITION PRODUCTS.

Spill Release Procedures:ABSORB WITH SAWDUST,EARTH,VERMICULITE ETC.
PLACE IN SEALED CONTAINER.DO NOT WASH DOWN PUBLIC SEWERS.IN HI-
CONCENTRATION SITUATION USE SELF CONTAINED GEAR OR AIR SUPPLY
RATHER THAN ORGANIC CHEMICAL TY PE RESPIRATORS. (HMIS-PROVIDE
VENTILATION-HMIS)
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:ENSURE GOOD VENTILATION.STORE IN COOL
PLACE. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.DO NOT
SMOKE.(HMIS-AVOID BREATHING VAPORS-HMIS)
Other Precautions:NOT:VAPOR HEAVIER.THAN AIR.ENSURE GOOD VENTILATION,
ESPECIALLY IN PITS. (HMIS-VAPORS ARE HEAVY AND MAY ACCUMULATE.
PROTECT CONTAINERS FROM DAMAGE DURING STORAGE. PREVENT LEAKAGE OR
SPILLAGE WHICH CAN RESULT OXYGEN DEPLETION. HMIS)

Respiratory Protection:SELF CONTAINED IF TLV IS EXCEEDED. (HMIS-ABOVE
1, 000 PPM, USE SELF-CONTAINED BREATHING APPARATUS. (HMIS)
Ventilation:ABOVE TLV-LOCAL RECOMMENDED.BELOW TLV-GEN MECHANICAL.
(HMIS- USE ADEQUATE VENTILATION. LOCAL EXHAUST FOR SMALL WORK AREA
Protective Gloves:PVC
Eye Protection:SAFETY GLASS W/S.SHIELDS
Other Protective Equipment:NONE SPECIFIED
Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS
PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING.
Supplemental Safety and Health
MSDS FM MFR DATED:2/22/78. (HMIS 1/10/95- FREON MAY DILUTE OR DISPLACE
OXYGEN BELOW LEVELS NECESSARY TO SUSTAIN LIFE. HMIS.)

HCC:N1
Boiling Pt:B.P. Text:118F,48C
Vapor Pres:270
Vapor Density:6.75
Spec Gravity:1.6
Evaporation Rate & Reference:NOT DETERMINED
Solubility in Water:0.017%
Appearance and Odor:COLORLESS LIQUID-FAINT ETHEREAL ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
SODIUM,POTASSIUM,BARIUM,HIGHLY REACTIVE METALS
Stability Condition to Avoid:NAKED FLAME OR HOT SURFACES. (HMIS-HEAT
WILL DECOMPOSE PRODUCT ABOVE 250F)
Hazardous Decomposition Products:HYDROGEN FLUORIDE,HYDROGEN CHLERIDE

Waste Disposal Methods:LANDFILL IN COMPLIANCE WITH LOCAL,STATE &
FEDERAL REGULATIONS OR RECOVER CONTAMINATED SOLVENT BY
DISTILLATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.